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三(二亚苄基丙酮)二钯(0)
产品编号:Pd003
化学名 Tris(dibenzylideneacetone)dipalladium(0) 
CAS号 51364-51-3 
别名 三(二亚苄基丙酮)二钯 
分子式 C51H42O3PD2 
分子量 915.70 
三(二亚苄基丙酮)二钯(0)
Chemical Formula: (C6H5CH=CHCOCH=CHC6H5)3Pd2
Color and Form:    purple pwdr.  深紫色粉末,溶于二氯甲烷或者氯仿后呈紫色
Stability: air & moisture sensitive
Physical Characteristics: melting point 152-155°C
Technical Notes:    
Tris(dibenzylideneacetone)dipalladium(0) (Pd2(dba)3) participates in the synthesis of azepane. Crystal structure of Pd2(dba)3 has been determined by three-dimensional X-ray data. Crystals of Pd2(dba)3 are reported to crystalize in triclinic system. It is widely used Pd(0) source in Pd-mediated transformations.
1. Catalyst precursor for conversion of aryl chlorides, triflates, and nonaflates to nitroaromatics.
2. Catalyst for the synthesis of epoxides.
3. Catalytic asymmetric allylic and homoallylic diamination of terminal olefins.
4. Site-selective benzylic sp3 palladium-catalyzed direct arylation.
5. Palladium-catalyzed one-pot synthesis of tricyclic indolines.
6. Active catalyst for the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles.
7. Catalyst in combination with BINAP for the asymmetric Heck Arylation of olefins.
8. Precursor for palladium-catalyzed carbon-nitrigen bond formation.
9. Catalyst for α-arylation of ketones,
10. Cross-coupling of aryl halides with aryl boronic acids.
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